In my BIOS all the voltages like the 12v and 3.3v all read about where they should be but after windows loads up theyre all lower then the BIOS shows. No matter what monitoring program i use theyre all lower except the 5v one. The 3.3V is at 3.1V and the 12V is at 11.49V. Ive also noticed that the Vcore for the CPU drops from 1.42V to 1.36V when im playing a game or running prime95. My psu is fine as its only about a month old and its an OCZ StealthXStream 700 Watt psu. I've also tested the psu on another comp and all the voltages check out on that comp.
Edit: My Motherboard is an Asus P4S800
Edit: My Motherboard is an Asus P4S800