What is the price for the second HD4870?
Why do you think you need to upgrade to an fire rig or an HD5870?
Can you wait for launch prices to come down in a bit few weeks?
I definitely wouldn't be buying a second HD4870 for Xfire right now, especially ince there will likely be a glut of them on eBay once all the new HD5870 buyers sell their old cards.
To which end you can also think of financing an HD5870 purchase by selling your old HD4870 on eBay if price is a concern.
Overall HD5870 > HD4870 in Xfire, maybe not always in performance, but less headaches with no Xfire to worry about, more features, and less power consumption.