Are you running into any problems on current games? If not, I'd try waiting if it isn't urgent and saving up. Maybe in 6 months or so you'll be able to skip directly to ATI or NVidia DX11. 8800GTS to either of the above would improve a little, but probably not enough to justify the cost.
the 250 is not much better than what you have. The 4850 not going to give you a drastic improvement either but is better than the 250.
That were true if he had the 8800GTS 512mb (G92), but he has the 8800GTS 320mb (G80), so there will definitely be some improvements, but it won't be twice as fast (get the 4850 because it's cheaper and the 250 isn't really better.)
"The Radeon HD 4770 is able to beat the HD 4830 and the Geforce 9800 GT most of the time and sometimes even get on the level of cards that are more expensive like the Radeon HD 4850 or the Geforce 9800 GTX."