-1 masterjaw
Reference capacitors charge. Computer PSU use a step down transformer. 120/240 VAC are only on the input side - NO 120/240 Volt high capacitence capacitors on input side. On secondary - low voltage (Max dc output is the +12V which the avg person would no even feel).
When measuring with power applied - remember the golden rule - key one hand in pocket - or only use one hand to make measurement and if possible attach meter probes with power off, turn power on, read, remove power.
I AGREE with jsc in pointing out the AC input. I've been hit by the 120VAC more times than I can count. >20Kv, only once, 1 Kv to 10KV a couple of times.
Respect the voltage, but do not be afraid of it.