Once tubing is routed, make sure all fittings and clamps are tight. Begin filling your reservoir with water and cycle the pump via power. Most people unplug the ATX plug from their board (highly recommended) and jumper any green to black wire with a paperclip. You can also buy some specialized power supplies that provide minimal power to a single molex, these also work great. Regardless, you don't want any power going to anything other than your pump, if possible. Your fans might spin up, but that's fine. Cycle power on until the pump sucks the water almost all the way down, power off. Refill the res, repeat as necessary.
Make sure to note the location of the ATX tab in relation to each wire. Jumper the green wire (ATX tab up, 4th from the left) with any black wire. Personally, I jumper the adjacent black wire (ATX tab up, 3rd from the left) since it's closest, but green to any black will work:
Once you have the loop filled, you'll want to let it run in the above manner for several hours, checking every 15 minutes or so for the first hour. Overnight running would be good once you are sure there are no immediate leaks. Keep paper towels handy and around fitting areas...check for dampness. If none and you've leak tested for at least a few hours, you are likely good to go.