There is nothing to be worried or nervous about.
First thing is if you're sucessfully using your SSD then you're in good shape and have probably already experienced some excellent performance improvements.
As far as the AHCI - if you are able to use that setting for the drive interface in your BIOS, you will get the best performance. However, it is not guaranteed that it will work with your configuration.
The available settings are generally AHCI, SATA, IDE (in that order of preference). If you installed your OS on to the SSD using SATA or IDE, the chances are that AHCI may not work. Also, depending on the OS and your configuration, it may not like it.
In my machines, I have not been able to get AHCI to take on them. Yes, having them as SATA and IDE I am sacrificing some performance. However, the improvements are still enormous.
On one of my machines, I'm running Windows 2000 Server - the thing did not even exist when SATA came along - so even installing the OS clean, it wouldn't even see the SSD! I had to do backflips to get that one installed.
Anyhow, you can try to go in to the BIOS and just flip the setting to AHCI and see what happens when you boot. Either it will work and you're in business, or it will do a blue screen on you and you'll need to flip it back to the setting you currently have. From what I've heard, in general, you need to install your OS on to the system drive in AHCI mode to have the best chance of success.
As far as defragging, you should just be sure that your OS isn't doing it as part of a automatic process it runs. I'm not familiar with Vipre and TuneUp.