Here are the official power requirements for the new ATI Radeon HD 5850 video cards.
ATI Radeon™ HD5850 System Requirements:
PCI Express® based PC is required with one X16 lane graphics slot available on the motherboard
500 Watt or greater power supply with two 75 watt, 6-pin, PCI Express® power connectors.
600 Watt or greater power supply with four 75 watt, 6-pin, PCI Express® power connectors for ATI CrossFireX™ technology in dual mode.
The power supply recommendations are for an entire pc system
Corsair and Seasonic are two brands that have a reputation for high quality power supplies that consistently earn high marks in technical reviews. They are reliable, stable, and come with a 5 year warranty. Some of the newer models come with a 7 year warranty. Lately we've been seeing a few other brands offering some high quality units. One example would be the Antec Earthwatts and the Antec TruePower New models which are a major improvement over Antec’s older psu’s like the Basiq models.
Here is a link to an excellent explanation of multiple +12 volt rails:http://www.jonnyguru.com/forums/showthread.php?t=3990