You have to set up the drive first. I think it's the MBR like game junky said.
Is the drive blank? Was the drive blank?
You could use DISKPART to do a CLEAN function, only if the drive is blank, or you don't care what was on the drive.
Let us know, and I can draw up a step-by-step for you.
Like SuperNova said: if the drive had Windows 7 on it, and you installed Windows 7 to the SSD WHILE THE HDD was still plugged in, you have other issues.
Where is the "System Reserved" partition in Disk Management? SSD, HDD, or both?