Between those two I would go with the Athlon II. While the higher clock speed of the Phenom II will help out some in gaming, more and more games are using 2 cores, and the 3rd (and 4th cores) could be used for other background tasks.
My actual recommendation though, would be to get an
Athlon II X3. It's cheaper than both, faster than the quad-core, and has an additional core compared to the Phenom II.