Yes as ridiculous as it sounds some games will benefit from you increasing the GPU settings AA/AF etc.
If you are being held back a bit by the CPU then giving the GPU more to do can in some cases help the CPU to cope. This works very basically because the CPU needs to feed data to the GPU before it can render a frame.
If the GPU can do this faster than the CPU can keep up then you get lagging etc while the card is waiting. Giving the card more to do takes it that fraction longer and in some cases this is all the CPU needs to help it keep up.
Of course you could always just check and see if you have V-Sync enabled, if not then doing so could help.
Mactronix