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For the network card should I stick with Onboard or go with a Killer Xeno Pro? Is it worth the $99.
Not going to be able to get to a full build right now, but here are a couple of thoughts.
The 980X is probably overkill, even for multi-boxing. I would expect that you could get by just fine with an i7-930 and overclocking it. The UD9 is also overkill, unless you plan on doing some really high-end overclocking. The UD3 or UD5 is more than enough for most people.
I would start off with one 480. I currently run 30 fps in Dalaran (at primetime, graphics on Ultra at 1920x1200) with an AMD Phenom II X4 + ATI 5870. 10 man ICC averages about 50-60fps, though it will drop if there are enough effects going off. I'd leave the option open to SLI another 480 later, but starting with 2 will probably be overkill, especially for your multiboxing.
Similarly, 24 GB is overkill. Since you're multiboxing, I'd get 12 GB, but not 24. Get 3 sticks of 4 GB each so that you can upgrade to 24 GB later if you find that you're really hurting. Socket 1366 uses triple-channel memory, so you want 6 GB, 12 GB, or 24 GB (sets of 3 sticks), not 8 GB...that would drop you to single-channel mode and could impact gameplay a little. Clock speed and CAS Latency are of about equal importance on Intel builds.
At 120-128 GB, the current best SSD is either the
OCZ Vertex 2 or the
Crucial C300 - excellent sale price right now.
Some "light" SSD reading:
Anandtech's SSD Relapse - a good overview of the technology, but a few months old, so the product recommendations are a bit dated.
bit-tech SSD Buyer's Guide - pretty recent, good overview of the various controllers
techreport article on SSD value - recent, includes comparisons vs. traditional HDDs.
Most people are finding modern onboard sound is fine for gaming. I'd go without the sound card, if you find it's really not working for you, you could always add one later.
The network card is absolutely not worth it. At best, it will decrease your ping by a couple of ms, which won't be noticeable to your eye/reflexes. When I say a couple, I mean 1ms-2ms. All it can do is affect the traffic on your LAN. It can't do anything to the signal once it hits your router and is on the internet. You would be much better served by spending that money to upgrade your internet connection. The only situation in which you might consider buying one of those is if you lug your rig around to LAN parties with a dedicated server, where a couple of ms might actually make the difference between fragging your buddy or not.