For a while there, companies were making power-supplies that did just this. They would fit in your computers 5.25" bay and would provide an extra 200W+ for PCIe-graphics cards. Something like this (note that they no longer sell it)
http://www.newegg.com/Product/Product.aspx?Item=N82E168...
Like reccy said, if you did add another PSU, you have to synchronize both PSUs so that they power-on at the same time, which could be difficult.
However, if you are going to buy an entire second PSU to power only the GPUs, why not just buy 1 PSU that's powerful enough for the whole system?