First of all, the RAM is running at it's stock speed, which is prety much always 1333mhz. To achieve the 2000mhz you need to enter your BIOS and start making changes. 1333mhz (667x2) ties into your base clock, which is generally 133 at stock. 160 is easy to achieve (for 1600mhz RAM). If you want the RAM to run at it's speed of 2000mhz, you'll have to up the base clock to 200. If doing that, you might have issues. Chances are it'll run fine if you disable turbo boost, and you might want to manually adjust the voltages rather than leaving on auto. You'll also need an aftermarket cooler to deal with the heat.
There's a lot of guides on overclocking, so you'll have to look into it.
I recommend for now going into the BIOS and trying 160 base clock, auto voltages, and then set your RAM timings as low as you can. Since it's 2000mhz RAM, what is the timing rating? I'll assume CL9 (as in 9-9-9-27), so going down to 1600mhz you can probably get CL7 (7-7-7-21). The speed should be around the same at the slower speed with faster timings. Alternatively, if you don't want to touch the CPU speed, you can probably set the 1333mhz RAM to CL5 or so (5-5-5-15) maybe CL6.
If you do that, make sure to download CoreTemp and/or HWMonitor and Intel Burn Test to check stability. Also Prime95 is a good idea. Make sure your temps aren't too high - if they are, like I said previously, an aftermarket cooler is in order.
To check if you have RAM issues, download Memtest86+. It requires you to put it on a boot disc/usb and then boot off it. This will let you know if you have memory issues (1 pass should be enough, if there's issues they usually crop up fairly fast)
Your freezing issue may or may not be GPU related, I don't know. If possible you can try MSI Afterburner and FurMark testing but I really don't know if a workstation GPU will work with those. If they do, freezing like that sounds like a VRAM issue and lowering the RAM clock can sometimes help. However, a new GPU might be the better fix since I don't have a clue if that card is any good for workstations... it's just not in my area of knowledge.
I hope this helps a bit.
EDIT: About the SATA6, I did a quick search and found this
http://benchmarkreviews.com/index.php?option=com_conten...
it says:
Quote:
Revision 3.x SATA 6Gb/s (SATA-III) has also been added onto the X58-Express platform, allowing enthusiasts to enjoy faster top-end bandwidth speeds from capable Solid State Drive storage devices. Instead of waiting for Intel to add SATA-6G support into their upcoming X68-Express platform planned for 2011, ASUS includes support on the P6X58D-Premium X58 motherboard right now by utilizing the Marvell 88SE9123-NAA2 SATA-6Gbps controller.
So basically, the "6" refers to the transfer speed, but the devices is a SATA 3 controller. Your HDDs are going to limit it tho, as HDDs cannot saturate that much bandwidth. You'll need SSDs to really utilize it, even then I don't think SSDs can saturate 6gb/s. So, your HDDs should be running at their maximum as it is.