Other than boot device selection you should be able to select the order of the hdds/ssds.
BTW, did you do a clean install of OS or clone the old hdd to ssd?
Yes it was a clean install, the SSD is running win7 Ultimate 64 bit. The HDD WAS running XP.
Okay thanks for your help, but I just switched the SATA cable that the HDD was using, then switched the SATA ports for the HDD and SSD, the HDD is now on port 4, and the SSD is now on port 5, no idea how this helped