Two things - one, did you install the application profiles; and two, go to the CCC menu in the system tray and turn on the display Crossfire graphic. That displays an ATI in the upper right corner if the driver enters Crossfire mode.
No I did not install the application profiles, don't know how, don't know anything about that. And the option to activate profiles is blocked out. also I turned on the crossfire graphic, there isn't one. once i enabled the feature no new icon showed up. just the icon in the system tray for ccc