Unless you need the extra RAM or just have some money burning a hole in your pocket stick with what you have. Your not going to get any real noticable difference by adding another stick.
Is it worth it to get a second 4GB stick to increase performance?
Only get a module with the exact same memory timings and voltage. Even then it's not guaranteed to work properly. A dual channel kit is the best way to go.
At most, dual channel will give you up to a 5% increase in memory performance.