I don't quite understand your question here...
But, you need to populate the correct RAM slots, as rolli said. You need two perfectly identical RAM sticks, and place them in the same coloured slots. Your motherboard should have four slots, two of them one colour and the other two another colour. These colours indicate the same slots of different channels, and as such you must place the sticks in the same coloured slots.
Then, with regards to the 1066MHz RAM running at 800MHz, it would seem as if you are running DDR2 memory. In DDR2 RAM slots, you won't gain much from 800MHz to 1066MHz, in fact, it's quite irrelevant. I wouldn't recommend overclocking the motherboard to accompany the RAM, as you seriously won't see much difference in games at all. Rather keep it at 800MHz and look at slight overclocking of your CPU if you want a little more speed.