The first thing for you to do is tell us the model of your motherboard and the rest of the specs of the system if you know them. If its a prebuilt system (Dell. HP, Gateway, etc...) then you can give us the brand and the model and we can look up the specs.
Depending on how new that pc is, there could be a problem with the motherboard supporting 4G modules.
Also give us the order you installed these upgrades such as HDD first then you later put in the ram, etc. This will help us rule out what works and what doesnt. If you went in and installed everything in at once and it wouldnt boot then you could go back and install the old memory modules to see if it will boot with that then that will let you know what to troubleshoot next.
You see, I just assumed you got a single 4G module but you obviously couldve gotten smaller modules. Just list the pc or motherboard model and the links to the items you installed if possible.