Intel® Z77 chipset :
2 x SATA 6Gb/s port(s), brown
4 x SATA 3Gb/s port(s), black
Support Raid 0, 1, 5, 10
ASMedia® ASM1061 controller : *5
2 x SATA 6Gb/s port(s), gray
How I would do it:
Connect the SSD to one of the Intel brown SATA ports, the 4 RAID HDDs to the Intel black ports, one optical drive to the available gray SATA port and the other one to the ASMedia gray SATA port (although the specs say that ATAPI devices are not supported).
Set SATA to RAID in BIOS, restart, use Ctrl+I to configure the RAID array, leave the optical device and the SSD as non-RAID, exit and start installing Windows.
Load the RAID driver during Windows install.
Install then the ASMedia driver.