When you have a card dedicated to Physx, it disables its ability to display as it only acts as an engine for processing the Physx requests from the game you're playing.
Unless he is willing to open the control panel and change the setting that is.
In other words, no, you cannot use it to watch TV while specifically playing a game that utilizes GPU accelerated PhysX with the GTX 260 dedicated to such. Other than that it should work fine if you just don't have it dedicated to PhysX in the settings when it's not needed for such.
You can switch between physics on GPU or on CPU. Setting physics to CPU will free up the extra video card.
Rember the clasic nvidia control panel that had a hotkey option. I used to use S+L+I all at the same time to turn SLI on and off so I could swtich between 1 focus screen and 3 screens quickly. (now adays you can run 3 screens even with SLI enabled so my example is sort of poor).
If the control panel still had that option you could set one where the 250 is a physics card, and one where physics is CPU based and the 250 is a secondary.