I dont know what that 14 at the end is, but If lets put it this way:
The 580 will give you now a more solid performance over all (lack of driver issues related to crossfire, for example). If in the future you will plan to add an extra 580, you will have a chance to get a monstrosity of a computer, assuming your PSU can handle it.
On the flipside, 6950 in crossfire will give you better performance than a single 580, however next time you will probably ONLY have the option to get a new generation of gpu, where with 580 you have kinda both options.
Personally, if id have a powerfull PC apart from this (I5-2500K, A SSD, etc), id probably get the 6950 in crossfire since i "would not want to change my computer for a while there".
Also note the diffrent tecnologies: Eyefinity? 3D? physx? MLAA?
Do you knwo them? and what would you like to have more?