Well, the good news is that all your other temps look fine. Your "Core" temp (in Speedfan) is obviously not correct but that happens sometimes with certain processors and motherboards. Mine reads 0 C all the time. Anyway, your Temp2 (speedfan) is essentially the same thing.
Either your CPU fan isn't spinning up enough to move air over the heatsink (unlikely) or the CPU cooler is making poor contact with the CPU.
I think you need to re-seat your CPU cooler. This will involve taking your cooler off, cleaning the old thermal compound (if there is any) off of the CPU and the cooler, applying new compound, and reinstalling it.
If you google "how install AM3 CPU cooler", you'll find some tutorials. You can use rubbing alcohol to remove the old thermal paste. Just be careful and make sure everything is good and dry before you apply the new paste. You can buy thermal paste at computer stores or maybe a local best buy. "Arctic Silver" is a common brand of paste.
Luckily, none of this is very expensive. Arctic Silver is really cheap and even if you need a new cooler, you won't be out very much $$.