Yes it will work, I think the question is does it provide value? I have 32 gigs of ram in my system, and i have never seen windows ever use more than 6gbs. Thats with games and movies and email and an access database running and so on.
32 gigs of ram is fun for making a 20 gig ram drive and running a game from it. All levels and matches load in like 1 second, but ram drives come with thier own challenges.