Hello,
Serious question here - why buy a pre-built?
For probably the same amount of money - you can probably get much better hardware depending on your budget.
Also - you can learn A LOT about computers by building them yourself. At least you would have this knowledge in the future - even though just starting out building your own computer can seem like a daunting task.
But, this is why this website exists - for us to help you out. We could help you out step-by step to get your own computer built.
But to answer your question if your dead set on going with a pre built, basically 2 graphics cards act like 1 - and -almost- gives double the performance of 1 card.
Even though each card is 1 GB, in SLI (Dual GPU mode) the OS will still only detect 1GB of GPU ram. This is because SLI mode copies the same information to both cards. Basically frame 1 will be by your first card, then frame 2 will be by your second card, then on the 3rd frame its back to your first card and so on. This is just a very basic run down of how dual GPU's work. It's much more complicated than that.
However there is a caveat to this - if your only running say 1920x1080 resolution - there really isn't a need to go with a dual GPU setup.
I would reccomend going with 1 bigger graphics card - like the GTX 670 (best bang for the buck at the moment).
A GTX 560TI will allow you to game out at medium/high settings depending on the game (and it's graphics settings) at 1920x1080.