Here is AMD's crossfire compatibility chart. Those cards would work fine. Usually you want the same GPU for optimal performance, but you will definitely see an increase. If you already have the card's though, toss them in. Just make sure you have an adequate power supply.
http://sites.amd.com/PublishingImages/Public/Graphic_Illustrations/WebBannerJPEG/AMD_CrossfireX_Chart_1618W.jpg