Dual Display with Nvidia

I have recently decided that sence I have this 25.5" Samsung monitor just sitting there doing nothing , because my wife is totally into using her laptop , I decided to try out dual monitors. I did set them up and they are working with the extended desktop and the mouse moves from one screen to the other and I can drag open windows from one screen to the other and have multiple windows open at once , so far so good.
The issue I am having is in gameing , when I open the game it only opens on one screen and not like I have seen on videos where it will span the two screens. Is this a Nvidia limitation and can only be done like that on AMD cards? The other monitor that I was using for my computer is a 27" LG and I have three GTX 580's in three way SLI. Is there another setting that I am missing and this is something that I have not tried or done before , any help will be appreciated.