First you need to estimate the power consumption per part, and with parts "potentially" electrically connected besides the data bus and a common ground, treat these as a combined "one" part for your calculations, else a bit of research about whether certain parts have common rails.
For example, you might take a multimeter and check continuity between your video card's 12V external power pin, and the CPU 12V, 4-pin connector. If there is no continuity between them, you can power them from different PSU. EDIT: Just be sure you have the right pins, and that your PSU is NOT plugged into anything yet, since it will obviously read continuous on a meter if you had the same PSU's 12V rail connected to both parts, even on most so-called split-12V-rail PSU.
Same for video card 5V, and motherboard ATX 20/24 pin connector 5V, pins... if there's no continuity between these, (which I would not assume as likely as separate 12V) again you can split which is supplied by which PSU- and it wouldn't be necessary for the same supply, supplying 12V to the card, to also supply 5V, but of course it might be a lot easier not having to start grafting individual power connectors between multiple PSU.
You might also consider powering some HDDs on a different PSU if there are several (more than 3), as the initial HDD spin-up draw is fairly high. No matter how you end up arranging it, you must have the grounds tied together, don't depend on both PSU having a good ground through the chassis-case or through the AC input ground.