AXP/Xion makes about three different versions of a 500W PSU and none of them are really good quality. They're made by a good OEM, Super Flower, but are definitely 'value' oriented...in this instance low quality and IMO low value because of the low quality. Does your PSU have a little red switch on the back of it for switching between 110V and 220V? Can you provide the specific model number of your PSU? There is a label on the side of the PSU that will list the model number. I personally would not use an AXP/Xion PSU...or allow it in the general vicinity of my components. I'd recommend getting a good quality PSU...it's the heart of any PC.
Why use two GPUs? SLI (nvidia tech) and Crossfire (AMD) allow you to put multiple graphics cards into a single PC and combine cards processing power for display onto a single large monitor or an array of monitors. The technology is good for high resolution gaming in graphics-intensive games. In order to do this you have to have two of the same model cards (in your case two GTX 560s or two GTS 450s and i'm not sure the GTS 450 is SLI capable). Bottom line if you don't know what it is , then don't worry about it. The technology doesn't scale well (i.e. two GTX 560s is not twice as powerful as a single GTX 560) and it is usually more cost effective to buy a single more powerful GPU.