It's called an Eyefinity set up. One monitor must be connected to the DisplayPort of your graphics card; either natively (your monitor has a diplayport input) or through the use of a displayport adapter.
If you are already utilizing such a set up, check in Catalyst Control Center to see if there is a setting to enable Eyefinity.
-Wolf sends
Edit: Specifically which HD6750 did you purchase? Could you provide a link?