I actually see it, although it's at the bottom and very hard to read.
Anyway, it looks like one program or the other has the sensors reversed. In this case, it actually looks like AI Suite is the on that's reversed.
AI Suite shows the motherboard temp at 33C and CPU at 22C (which shouldn't really be possible), and Game Booster shows them to be the exact opposite (22C motherboard temp and 33C CPU temp, which is a lot more believable).
Yeah, it's not detecting the right sensors and they're glitched, as well.
The ones you need to pay attention to are the cores and Package in the CPU temp section and those are just fine (Minimum could be better, but the max is perfect).
I'd just ignore the Non CPU "Temperature" section altogether because it's obviously not detecting the right CPU temp (and it's glitched, as evidenced by the +100C max temps. If it really got that hot, it would have shut down).