No, you cannot use the 6450 and 6670 together.
Also, the 6670 is a piece of junk, though the 6450 is even worse. It's definitely an upgrade, but I've got a feeling you'd be very disappointed with the results.
If you want gaming performance anywhere in the realm of "good" you're going to need to spend a good deal more money. A quality 450W unit should be able to handle a card like the 7770, which is a very good card for the low end space.