I'm using VMWare Workstation 8, but I think that it was identical in 7 as I recall.
VMWare has an online guide to configuring networking, and pretty much everything else in the guest OS VMs.
It's been a while since I've done it but it goes something like this. Run the Virtual Network Editor. Disable automatic bridging. Then, specify which physical NIC you want bridged to VMnet0; and specify the second physical NIC to bridge to one of the unused VMnetX (X=2-7, 9). In your VM settings, set one virtual NIC to the VMnet0, and set the other one to be Custom, and specify the other VMnet you set.