Actually, without any 3rd party tools, no. A lot of the commands from the prompt are not available from the GUI or if they are, you need 10 steps to get to them.
Try to perform some tasks that you believe you will be doing, then try to find the relevant commands on a search engine and see how other people use them.
Also, don't forget to use the very helpful /? or -? next to the command to see all the switches or abilities.
Good luck and welcome to the club!