Digital is always better than analog because less distortion and signal loss. The following are what I understand -
MP3 PLAYBACK: The music quality has been compressed down to 96-128k bitrate, so basically analog output would cause more signal loss but not signficantly. So there shouldn't be much different, at least not something that human ear can differentiate.
CD PLAYBACK: Digital is bettter because CD audio is digital signal (Pro Logic 2 is analog I believe). The best way is use digital audio cable to connect your CD-ROM/DVD-ROM to SPDIF input on your mobo/sound card then connect the spaeker using digital output. By this way you will not suffer from no quality loss. I'll give an illustration:
Analog way: Digital source (CD) -> analog CD_in (mobo/soundcard header)***quality loss*** -> analog output***more quality loss***
Digital way: Digital source (CD) -> SPDIF_in (mobo/soundcard header)***no quality loss*** -> digital output***no quality loss***
DVD-AUDIO: I think you mean DVD movie. Digital is still better. DVD movies sound stream are digitally encoded to AC3, therefore you'll get true realtime Dolby Digital 5.1/6.1/7.1ch sound encoding. For Dolby Surround Pro Logic (analog), the digital sound has to be decoded and then converted to analog output ***quality loss***. I'm not expert on this but I believe true digital sound (384k) is batter then DAC sound (192k) and in case of Audigy2 is even worse (96k).
PC-GAMING: OK, for this analog may be better unless the soundcard itself can do realtime decoding. Let me put in this way, the positioning sound from most games is sort of like "pre-coded" so you'll get 3D effect. But if your soundcard can do realtime digital decoding (like SoundStorm from nVidia) then you will still get 3D effect from digital output. In fact I connect my Creative Cambridge Soundworks DTT3500 via digital coaxial output from my on-board SoundStorm and I get positioning effect when playing games like Max Payne, NFS: Hot Pursuit 2, Warcraft 3 etc.
Finally, I'm sure Z-680 has an external receiver/decoder and this receiver/decoder is capable to do realtime decoding even if your soundcard can't.
All of above is based on my own knowledge, it may be incorrect but one thing I'm sure is that digital is NOT only stereo and as a matter of fact true digital can do stereo/2.1/4.1/5.1/6.1/7.1 channel audio processing.
You never know how stupid you are until you have done something stupid enough for you to realize it.
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