How to use samsung kies to connect to internet from samsung GT-E2232 with out wi

You can't, Kies program is for synching data only, it is not used for tethering. If you want to tether your phone, ask the cell phone service provider you are using how to do that.

Through Samsung Kies, you can take backup of your contacts, songs, videos, messagesetc. In short you can sync your phone with Kies.