ATA133 is a standard dreamed up by Maxtor and VIA. The "standard" standard is ATA100. That's why you don't see as many ATA133 products as ATA100 on the market.
As for performance, drives are still chugging along at ATA66 speed for the most part, even with their faster interfaces. The only time faster speeds are really used is in transfers from drive cache, which still tend to peak between 100 and 110MB/s, hardly a difference from ATA100.
<font color=blue>Only a place as big as the internet could be home to a hero as big as Crashman!</font color=blue>
<font color=red>Only a place as big as the internet could be home to an ego as large as Crashman's!</font color=red>