Is there a way to set the affinity setting for certain programs?

I play modern warfare 2 and it works best on two corers not 4 but I have to set it to use only to cores every time I start the game and I want windows to only allow it to run on core 3 & 4 only is this possible
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More about affinity setting programs
  1. Once the game is running, alt-tab out and open the Task manager. Go to the Processes tab and find the process for MW2. Right click on it and click Set Affinity.
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Windows 7