Yes, I'm on a PCI-e 3.0 (the board has 5). I'm on the z77x-up7, and using the black (single-card) slot.
I'm also running win7pro-64.
Driver:
9.012-121219a-152192C-ATI
Catalyst 13.1
Oddly enough, the full 6GB is identified in Catalyst (under Information->Hardware).