CyberYotta said:
CPU
Intel Core i5-4670K 3.4GHz Quad-Core Processor
Motherboard
MSI Z87-G45 Gaming ATX LGA1150 Motherboard
Memory
Corsair Vengeance 4GB (2 x 2GB) DDR3-1600 Memory
Corsair Vengeance LP 4GB (1 x 4GB) DDR3-1600 Memory
Storage
Seagate Barracuda 7200.10 160GB 3.5" 7200RPM Internal Hard Drive
Seagate Barracuda 1TB 3.5" 7200RPM Internal Hard Drive
Video Card
Asus GeForce GTX 750 Ti 2GB Video Card
Case
Thermaltake Chaser A71 ATX Full Tower Case
Power Supply
Cooler Master V850 850W 80+ Gold Certified Fully-Modular ATX Power Supply
Operating System
Microsoft Windows 8.1 Professional (32/64-bit)
Yeah, this will work.
That PSU is totally overkill for a GX 750 Ti, even if you go dual-SLI with it. A better choice would be a 350W or 450W PSU. If you decide to SLI the 750 Ti then a 750W PSU should be good enough. I would recommend a PSU by Corsair, Seasonic, Antec or XFX since they make better quality PSUs that have a lower probability of failing. The Corsair RM450 is a good option.
If you want 8GB of RAM then get a 2x8GB set. You will save money that way and it should also be a little more stable if you're overclocking since it's an LGA1150 motherboard.
Also, unless you're going for a RAID configuration on your hard drives (which I assume you're probably not), I think you should just get a single 2TB hard drive or, even better, go for a 1TB hard drive and get a 120GB SSD like the Samsung 840 Evo 120GB.