should i replace cpu/gpu for better performance in games

PCPartPicker part list / Price breakdown by merchant

Video Card: Sapphire Radeon R9 390X 8GB Tri-X Video Card ($434.98 @ Newegg)
Power Supply: EVGA SuperNOVA NEX 750W 80+ Bronze Certified Semi-Modular ATX Power Supply ($54.99 @ NCIX US)
Total: $489.97
Prices include shipping, taxes, and discounts when available
Generated by PCPartPicker 2015-07-01 04:02 EDT-0400

I would get that, however i dont know what the prices/availability of those are where you live. a psu thats atleast 650w from corsair, evga, seasonic, antec, or xfx will be fine, plus an R9 390x, or non-x if you cant afford it.