What are the correct voltage values for a pc power supply

It is 5% voltage tolerance so 11.4-12.6 for the +12 V rail, 4.75-5.25 for the +5V rail, and 3.135-3.465 for the 3.3V rail. Ideally you would like them to be as close to their nominal values as possible but they are allowed to sit anywhere in that range, but their value will change as the load on the PC changes so if it is low in the allowed range it could drop below acceptable limits once under load.